I'm with Spider-Man (2002) because it came out in 2002, it's an Early-2000's CLASSIC and aside from Willem Dafoe's Green Goblin Costume (WHICH ISN"T AS BAD AS MANY MAKE IT TOO BE) I feel it aged MUCH BETTER than Spider-Man 2 and I feel Sam Raimi captured who the character is supposed to be MUCH BETTER than Spider-Man 2 (2002).
AS great and as fun as Alfred Molina's Doc Ock was...he was really just a Green Goblin 2.0 and Doc Ock isn't supposed to be a good guy-gone bad, he isn't so supposed to be sympathetic. Plus, Spider-Man (2002) has Willem Dafoe at his most over-the-top/crazy as shit best and WHO DOESN'T LOVE THAT.